Beryllium nitride
 | |
| Identifiers | |
|---|---|
1304-54-7  | |
| ECHA InfoCard | 100.013.757 |
| Properties | |
| Be3N2 | |
| Molar mass | 55.06 g/mol |
| Appearance | yellow or white powder |
| Density | 2.71 g/cm3 |
| Melting point | 2,200 °C (3,990 °F; 2,470 K) |
| Boiling point | 2,240 °C (4,060 °F; 2,510 K) (decomposes) |
| decomposes | |
| Solubility in [[acids, bases]] | hydrolyzes |
| Structure | |
| Cubic, cI80, SpaceGroup = Ia-3, No. 106 (α form) | |
| Hazards | |
| US health exposure limits (NIOSH): | |
| PEL (Permissible) |
TWA 0.002 mg/m3 C 0.005 mg/m3 (30 minutes), with a maximum peak of 0.025 mg/m3 (as Be)[1] |
| REL (Recommended) |
Ca C 0.0005 mg/m3 (as Be)[1] |
| IDLH (Immediate danger) |
Ca [4 mg/m3 (as Be)][1] |
| Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
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| Infobox references | |
Beryllium nitride, Be3N2, is a nitride of beryllium. It can be prepared from the elements at high temperature (1100–1500 °C),[2] unlike Beryllium azide or BeN6, it decomposes in vacuum into beryllium and nitrogen.[2] It is readily hydrolysed forming beryllium hydroxide and ammonia.[2] It has two polymorphic forms cubic α-Be3N2 with a defect anti-fluorite structure, and hexagonal β-Be3N2.[2] It reacts with silicon nitride, Si3N4 in a stream of ammonia at 1800–1900 °C to form BeSiN2.[2]
Preparation
Beryllium nitride is prepared by heating beryllium metal powder with dry nitrogen in an oxygen-free atmosphere in temperatures between 700 and 1400 °C.
Uses
It is used in refractory ceramics[3] as well as in nuclear reactors and to produce radioactive carbon-14 for tracer applications.
Reactions
Beryllium nitride reacts with mineral acids producing ammonia and the corresponding salts of the acids:
- Be3N2 + 6 HCl → 3 BeCl2 + 2 NH3
In strong alkali solutions, a beryllate forms, with evolution of ammonia:
- Be3N2 + 6 NaOH → 3 Na2BeO2 + 2 NH3
Both the acid and alkali reactions are brisk and vigorous. Reaction with water, however, is very slow:
- Be3N2 + 6 H2O → 3 Be(OH)2 + 2 NH3
Reactions with oxidizing agents are likely to be violent. It is oxidized when heated at 600 °C in air.
References
- 1 2 3 "NIOSH Pocket Guide to Chemical Hazards #0054". National Institute for Occupational Safety and Health (NIOSH).
- 1 2 3 4 5 Egon Wiberg, Arnold Frederick Holleman (2001) Inorganic Chemistry, Elsevier ISBN 0-12-352651-5
- ↑ Hugh O. Pierson, 1996, Handbook of Refractory Carbides and Nitrides: Properties, Characteristics, Processing, and Applications, William Andrew Inc.,ISBN 0-8155-1392-5