7-epi-alpha-selinene synthase
7-epi-alpha-selinene synthase | |||||||||
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Identifiers | |||||||||
EC number | 4.2.3.86 | ||||||||
Databases | |||||||||
IntEnz | IntEnz view | ||||||||
BRENDA | BRENDA entry | ||||||||
ExPASy | NiceZyme view | ||||||||
KEGG | KEGG entry | ||||||||
MetaCyc | metabolic pathway | ||||||||
PRIAM | profile | ||||||||
PDB structures | RCSB PDB PDBe PDBsum | ||||||||
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7-epi-alpha-selinene synthase (EC 4.2.3.86) is an enzyme with systematic name (2E,6E)-farnesyl-diphosphate diphosphate-lyase (7-epi-alpha-selinene-forming).[1][2] This enzyme catalyses the following chemical reaction
- (2E,6E)-farnesyl diphosphate 7-epi-alpha-selinene + diphosphate
The recombinant enzyme from Vitis vinifera forms (+)-valencene and (-)-7-epi-alpha-selinene.
References
- ↑ Lucker, J.; Bowen, P.; Bohlmann, J. (2004). "Vitis vinifera terpenoid cyclases: functional identification of two sesquiterpene synthase cDNAs encoding (+)-valencene synthase and (-)-germacrene D synthase and expression of mono- and sesquiterpene synthases in grapevine flowers and berries". Phytochemistry. 65: 2649–2659. doi:10.1016/j.phytochem.2004.08.017. PMID 15464152.
- ↑ Martin, D.M.; Toub, O.; Chiang, A.; Lo, B.C.; Ohse, S.; Lund, S.T.; Bohlmann, J. (2009). "The bouquet of grapevine (Vitis vinifera L. cv. Cabernet Sauvignon) flowers arises from the biosynthesis of sesquiterpene volatiles in pollen grains". Proc. Natl. Acad. Sci. USA. 106 (17): 7245–7250. doi:10.1073/pnas.0901387106. PMID 19359488.
External links
- 7-epi-alpha-selinene synthase at the US National Library of Medicine Medical Subject Headings (MeSH)
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